Episode Summary: As the summer is drawing to a close, Blair and Chuck are madly in love and adjusting to their new "in a relationship" status, breaking all the traditional rules of dating as would be expected.
Season 3, Episode 2: The Freshmen
Episode Summary: Blair, who is determined to maintain her Queen status in college, embarks on her first day at NYU, along with Dan and Vanessa. Unfortunately, Georgina turns up as Blair's roommate in the dorms, determined to make Blair a social outcast.
Season 3, Episode 3: The Lost Boy
Episode Summary: It's an Upper East Side face-off when Blair and Chuck both set their sights on a particular item up for bid at Sotheby's and the personal stakes are high.
Season 3, Episode 4: Dan de Fleurette
pisode Summary: On the first day of school at Constance Billard, Jenny is forced to make her rightful place as the new Queen Bee of the Mean Girls. Unfortunately for Jenny, Blair is more than happy to intervene when news reaches her that Jenny may need her help.
Season 3, Episode 5: Rufus Getting Married
Episode Summary: Lily and Rufus decide to move up their wedding to the next day, but a series of complications threaten to tear them back apart again.
Season 3, Episode 6: Enough About Eve
Episode Summary: Vanessa and Blair both take to scheming to be given the honor of giving the freshman toast at NYU.
Season 3, Episode 7: How to Succeed in Bassness
Episode Summary: Chuck decides to move up his hotel nightclub's opening and enlists Serena's help to get the word out to her celebrity clients for publicity reasons. Feeling left out of the planning, Blair attempts to win Chuck's approval by secretly helping him with a problem concerning opening night.
Season 3, Episode 8: The Grandfather: Part II
Episode Summary: Olivia says something she regrets during her appearance on Jimmy Fallon's TV talk show and tries to keep Dan from finding out. With the local election day around the corner, Nate suspects that his grandfather will stop at nothing to get his cousin Trip elected to congress.
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Season 3, Episode 9: They Shoot Humphreys, Don't They?
Season 3, Episode 10: The Last Days of Disco Stick
Episode Summary: Hoping to impress the elitist theater kids at NYU, Blair sets her sights on landing a private concert with the hottest musical performer of the year, Lady Gaga.
Season 3, Episode 11: Treasure of Serena Madre
Episode Summary: As Thanksgiving draws near, Blair suspects her mother, Eleanor, has been keeping a big secret from her, but it turns out to be something else entirely.
Season 3, Episode 12: The Debarted
Episode Summary: On the anniversary of Bart Bass' death, Chuck wrestles with the dilemma of following his conscience, or that of his father. Serena begins to suspect in Trip, when thank Nate, discovers that has been joined by Maureen.
Season 3, Episode 13: Jenny, Full of Grace
Season 3, Episode 14: The Lady Vanished
Season 3, Episode 15: The Sixteen Year Old Virgin
Season 3, Episode 16: The Empire Strikes Jack
Season 3, Episode 17: Inglourious Bassterds
Season 3, Episode 18: The Unblairable Lightness of Being
Season 3, Episode 19: Dr. Estrangeloved
Season 3, Episode 20: It's a Dad, Dad, Dad, Dad World
Season 3, Episode 21: Ex-Husbands and Wives
Season 3, Episode 22: Last Tango, Then Paris